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μ-3,3′-Bisacetylacetonato-bis[(1,10-phenanthroline)palladium(II)] bis(hexafluorophosphate) acetonitrile solvate.
- Source :
-
Acta Crystallographica: Section E . Oct2006, Vol. 62 Issue 10, pm2743-m2744. 1p. 3 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- In the title complex, [Pd2(C10H12O4)(C12H8N2)2](PF6)2·CH3CN, the PdII centre has a distorted cis square-planar geometry defined by an O, O′-bidentate bis­acetyl­acetonate dianion ligand and a chelating 1,10-phenanthroline ligand. The crystal structure features electrostatic inter­actions between the cations and anions, inter­molecular π–π inter­actions between pairs of 1,10-phenanthroline rings, and weak hydrogen bonds involving hexa­fluoro­phosphate anions (C—H⋯F) and the acetonitrile solvent mol­ecules (C—H⋯N). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 22675053
- Full Text :
- https://doi.org/10.1107/S1600536806039092