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μ-3,3′-Bisacetylacetonato-bis[(1,10-phenanthroline)palladium(II)] bis(hexafluorophosphate) acetonitrile solvate.

Authors :
Mei, Guang-Quan
Huang, Ke-Long
Huang, Hai-Ping
Source :
Acta Crystallographica: Section E. Oct2006, Vol. 62 Issue 10, pm2743-m2744. 1p. 3 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

In the title complex, [Pd2(C10H12O4)(C12H8N2)2](PF6)2·CH3CN, the PdII centre has a distorted cis square-planar geometry defined by an O, O′-bidentate bis­acetyl­acetonate dianion ligand and a chelating 1,10-phenanthroline ligand. The crystal structure features electrostatic inter­actions between the cations and anions, inter­molecular π–π inter­actions between pairs of 1,10-phenanthroline rings, and weak hydrogen bonds involving hexa­fluoro­phosphate anions (C—H⋯F) and the acetonitrile solvent mol­ecules (C—H⋯N). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
10
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
22675053
Full Text :
https://doi.org/10.1107/S1600536806039092