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Chemical predisposition in synthesis: application to the preparation of the pyrrolidine natural products, plakoridines A and B
- Source :
-
Tetrahedron . Nov2006, Vol. 62 Issue 47, p10914-10927. 14p. - Publication Year :
- 2006
-
Abstract
- Abstract: The pyrrolidine natural products, plakoridines A and B, as well as an array of unnatural analogues, have been prepared using a five-step synthetic sequence modelled on a biogenetic theory. The key transformation involves a ‘Mannich/Michael/internal-redox’ cascade, which proceeds in yields of 31–63%. [Copyright &y& Elsevier]
- Subjects :
- *PYRROLIDINE
*NATURAL products
*RAW materials
*ORGANIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 62
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 22716820
- Full Text :
- https://doi.org/10.1016/j.tet.2006.08.075