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catena-Poly[[diaqua(isonicotinato-κ2 O, O′)erbium(III)]-di-μ-isonicotinato-κ4 O: O′].
- Source :
-
Acta Crystallographica: Section E . Nov2006, Vol. 62 Issue 11, p3080-3082. 3p. 4 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- In the title compound, [Er(IN)3(H2O)2] n, where IN is the isonicotinate anion, C6H4NO2−, the asymmetric unit contains one half-mol­ecule. The ErIII atom lies on a crystallographic twofold axis and is coordinated by four and two carboxyl­ate O atoms from bridging and chelating isonicotinate groups, respectively, and by two O atoms from water mol­ecules, yielding an eight-coordinate square-anti­prismatic geometry. In the crystal structure, the polymer features an infinite doubly carboxyl­ate-bridged chain-like structure with one chelating carboxyl­ate group on each metal centre. Adjacent chains are, in turn, connected to each other through inter­molecular O—H⋯O and O—H⋯N hydrogen bonds, forming a three-dimensional network. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 22999985
- Full Text :
- https://doi.org/10.1107/S160053680604373X