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{Bis­[2-(3,5-dimethyl­pyrazol-1-yl)eth­yl]amine-κ3 N, N′, N′′}chloro­palladium(II) chloride dihydrate.

Authors :
Mendoza, María de los Angeles
Bernès, Sylvain
Mendoza-Díaz, Guillermo
Source :
Acta Crystallographica: Section E. Nov2006, Vol. 62 Issue 11, p2934-2936. 3p. 3 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

The title compound, [PdCl(C14H23N5)]Cl·2H2O, contains a four-coordinate palladium complex, in which the planes of the pyrazole rings are almost perpendicular. This is mainly a consequence of the close steric contacts between the methyl groups which would occur in the case of mirror symmetry, which are avoided by adopting a quasi-twofold rotation symmetry. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
11
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
23000144
Full Text :
https://doi.org/10.1107/S1600536806041985