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catena-Poly[[diaqua­(isonicotinato-κ2 O, O′)­dysprosium(III)]-di-μ-isonicotinato-κ4 O: O′].

Authors :
Bo Xu
Hui-Luan Liu
Qing-Hua Zheng
Guo-Ming Wang
Source :
Acta Crystallographica: Section E. Nov2006, Vol. 62 Issue 11, p2952-2954. 3p. 4 Diagrams, 2 Charts.
Publication Year :
2006

Abstract

The title dysprosium coordination polymer [Dy(IN)3(H2O)2] n, where IN− is the isonicotinate anion C6H4NO2−, has been hydro­thermally synthesized. The polymer exhibits a doubly carboxyl­ate-bridged infinite chain-like structure with the metal center lying on a crystallographic twofold axis and coordinating by two carboxyl­ate O atoms from a chelating isonicotinate group (also lying on a twofold axis), four carboxyl­ate O atoms from four bridging isonicotinate ligands, and two water mol­ecules, to yield an eight-coordinate square-anti­prismatic geometry. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
62
Issue :
11
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
23000165
Full Text :
https://doi.org/10.1107/S1600536806041559