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4,4′-Bipyridinium diaquabis(pyridine-2,5-dicarboxylato-κ2 N, O2)zincate(II).
- Source :
-
Acta Crystallographica: Section E . Dec2006, Vol. 62 Issue 12, pm3309-m3311. 3p. 2 Diagrams, 2 Charts. - Publication Year :
- 2006
-
Abstract
- Hydro­thermal reaction of Zn(NO3)2·6H2O with pyridine-2,5-dicarboxylic acid, 4,4′-bipyridine and pyridine in a 1:1:1:2 molar ratio affords the title complex, (C10H10N2)[Zn(C7H3NO4)2(H2O)2], in which both ions are centrosymmetric. The ZnII atom is octahedrally coordin­ated by two pyridine-2,5-dicarboxyl­ate chelating ligands and two water mol­ecules in a distorted octa­hedral geometry. 4,4′-Bipyridinium, acting as counter-ion, has hydrogen-bonding inter­actions with pyridine-2,5-dicarboxyl­ate, forming a three-dimensional structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 62
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 23414961
- Full Text :
- https://doi.org/10.1107/S1600536806047015