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Poly[[dicopper(II)-μ-4,4′-bipyridyl-bis[μ- N-(hydroxypropyl)propane-1,3-diamine]] bis(perchlorate)].
- Source :
-
Acta Crystallographica: Section E . Jan2007, Vol. 63 Issue 1, pm172-m174. 1p. 2 Diagrams, 2 Charts. - Publication Year :
- 2007
-
Abstract
- The title coordination polymer, {[Cu2(C6H15N2O)2(C10H8N2)](ClO4)2} n, was synthesized from 4,4′-bipyridine, N-hydroxypropyl-1,3-propanediamine and copper(II) per­chlorate. Structural analysis shows that each copper ion is coordinated by the 4,4′-bipyridine mol­ecule through one N atom, and by two N-hydroxypropyl-1,3-propanediamine ligands through the O atom and two N atoms of one, and the O atom from the second, giving a distorted square-pyramidal geometry. There are centres of inversion at the mid-points of the Cu2O2 ring and the bridging ligand. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 63
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 23615882
- Full Text :
- https://doi.org/10.1107/S1600536806053165