Back to Search Start Over

Poly[[dicopper(II)-μ-4,4′-bipyridyl-bis­[μ- N-(hydroxy­prop­yl)propane-1,3-diamine]] bis­(perchlorate)].

Authors :
Zhang, Zhen-Ming
Wang, Da-Qi
Jian, Gao
Li, Shuan
Source :
Acta Crystallographica: Section E. Jan2007, Vol. 63 Issue 1, pm172-m174. 1p. 2 Diagrams, 2 Charts.
Publication Year :
2007

Abstract

The title coordination polymer, {[Cu2(C6H15N2O)2(C10H8N2)](ClO4)2} n, was synthesized from 4,4′-bipyridine, N-hydroxypropyl-1,3-propanediamine and copper(II) per­chlorate. Structural analysis shows that each copper ion is coordinated by the 4,4′-bipyridine mol­ecule through one N atom, and by two N-hydroxypropyl-1,3-propanediamine ligands through the O atom and two N atoms of one, and the O atom from the second, giving a distorted square-pyramidal geometry. There are centres of inversion at the mid-points of the Cu2O2 ring and the bridging ligand. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
1
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
23615882
Full Text :
https://doi.org/10.1107/S1600536806053165