Back to Search
Start Over
Novel Copper-Complex-Substituted Tungstogermanates.
- Source :
-
Inorganic Chemistry . 2/5/2007, Vol. 46 Issue 3, p616-618. 3p. - Publication Year :
- 2007
-
Abstract
- Two copper-complex-substituted tungstogermanates [Cu5(2,2′-bpy)6-(H2O)][GeW8O31]•9H2O, 1, and {[Cu5(2,2′-bpy)5(H2O)][GeW9O34]}2• 7H2O, 2 (2,2′-bpy = 2,2′-bipyridyl), have been hydrothermally synthesized and structurally characterized. X-ray structural analyses show that 1 is a rare tetralacunary Keggin anion of [B-β-GeWBO31]10- substituted by copper complexes, while dimer 2 consists of two trilacunary [B-α-GeWgO34]10- Keggin units bridged by copper complexes. Magnetic measurement for 2 shows the presence of antiferromagnetic interactions within the dinuclear Cu2+ cations. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 46
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 23963788
- Full Text :
- https://doi.org/10.1021/ic0618605