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catena-Poly[[dichloridodimethyl­tin(IV)]-μ-5-methyl­pyrazine-2-carboxyl­ato-κ3 O: O′, N-[dimethyl­tin(IV)]]-μ-5-methyl­pyrazine-2-carboxyl­ato-κ3 O, N: O′].

Authors :
Jun-Ying Li
Tian-Duo Li
Source :
Acta Crystallographica: Section E. Mar2007, Vol. 63 Issue 3, pm847-m849. 1p. 2 Diagrams.
Publication Year :
2007

Abstract

The title compound, [Sn2Cl2(CH3)4(C6H5N2O2)2], forms infinite one-dimensional zigzag chains that propagate in a helical fashion along the c axis via an Sn—O=C—O—Sn—O bridge which involves the carboxyl­ate groups of two methyl­pyrazine­carboxyl­ate ligands. These display both chelating and bridging coordination behaviour. The asymmetric unit contains two Sn atoms; one adopts a distorted trigonal–bipyramidal geometry, while the other is in a distorted penta­gonal–bipyramidal configuration. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
3
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
24270727
Full Text :
https://doi.org/10.1107/S1600536807007866