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catena-Poly[[dichloridodimethyltin(IV)]-μ-5-methylpyrazine-2-carboxylato-κ3 O: O′, N-[dimethyltin(IV)]]-μ-5-methylpyrazine-2-carboxylato-κ3 O, N: O′].
- Source :
-
Acta Crystallographica: Section E . Mar2007, Vol. 63 Issue 3, pm847-m849. 1p. 2 Diagrams. - Publication Year :
- 2007
-
Abstract
- The title compound, [Sn2Cl2(CH3)4(C6H5N2O2)2], forms infinite one-dimensional zigzag chains that propagate in a helical fashion along the c axis via an Sn—O=C—O—Sn—O bridge which involves the carboxyl­ate groups of two methyl­pyrazine­carboxyl­ate ligands. These display both chelating and bridging coordination behaviour. The asymmetric unit contains two Sn atoms; one adopts a distorted trigonal–bipyramidal geometry, while the other is in a distorted penta­gonal–bipyramidal configuration. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PYRIDAZINES
*METHYL groups
*LIGANDS (Chemistry)
*CHELATES
*COORDINATION compounds
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 63
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica: Section E
- Publication Type :
- Academic Journal
- Accession number :
- 24270727
- Full Text :
- https://doi.org/10.1107/S1600536807007866