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Origin of the superior hydrogenation selectivity of gold nanoparticles in alkyne + alkene mixtures: Triple- versus double-bond activation
- Source :
-
Journal of Catalysis . Apr2007, Vol. 247 Issue 2, p383-386. 4p. - Publication Year :
- 2007
-
Abstract
- Abstract: DFT simulations have uncovered the origin of the highly selective character of gold nanoparticles in hydrogenation of triple bonds. This is ascribed to the better adsorption of Cedges of Au nanoparticles compared with Cthe barriers for hydrogenation of triple and double bonds on gold are comparable, selectivity is determined by the binding energy of the reactants. The situation is less favorable over palladium (commercial hydrorefining catalyst), because both Ce:glyph name="tbnd" />C bonds are adsorbed on the Pd surface. The outcome of the simulations was demonstrated experimentally in mixtures with both propyne and propylene over a Au/CeO2 catalyst, where C3H6 selectivities up to 95% were attained. Our finding opens a new path for chemoselective hydrogenation of molecules containing -yne and -ene groups on gold, with prospective application in petrochemical operations and in the fine chemical industry. [Copyright &y& Elsevier]
- Subjects :
- *HYDROGENATION
*NANOPARTICLES
*PALLADIUM
*SYNTHETIC products
Subjects
Details
- Language :
- English
- ISSN :
- 00219517
- Volume :
- 247
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 24541302
- Full Text :
- https://doi.org/10.1016/j.jcat.2007.02.019