Synthesis, characterization and 1D helical chain crystal structure of [Cu(DBA)2(1,10-phen)] n and [Cd(DBA)2(1,10-phen)2] (DBA=benzilic acid)

Abstract: Two novel complexes [Cu(DBA)2(1,10-phen)] n (1) and [Cd(DBA)2(1,10-phen)2] (2) [HDBA=benzilic acid: (C6H5)2C(OH)COOH] have been synthesized and characterized by element analysis and fluorescence spectroscopy. The crystal structures of compounds 1, 2 and HDBA (3) were also determined. Complex 1 is a one-dimensional (1D) helical infinite chain, in which [(1,10)-phen]Cu(II) units were bridged by benzilic acid. Complex 2 is a mononuclear structure, and is self-assembled through π–π stacking interactions to form a 1D helical chain. Compound 3 is self-assembled to form a 1D helical chain through hydrogen bonds interactions. Thermal analyses indicate that complexes 1 and 2 are stable under 200 and 254°C in solid state, respectively. [Copyright &y& Elsevier]