On the use of 2D correlation and exchange NMR spectroscopy in organic porous materials

Abstract: Two-dimensional (2D) nuclear magnetic resonance (NMR) methods for the investigation of correlation and exchange have been introduced in recent years and have been applied to a range of different systems. Here, we report on the use of 2D NMR diffusion–diffusion correlation spectroscopy for the investigation of diffusion anisotropy in cellular plant tissues and of diffusion–diffusion exchange spectroscopy for the study of the diffusive exchange of dextran in a dispersion of polyelectrolyte multilayer hollow capsules. Furthermore, diffusion–relaxation correlation spectroscopy was applied to both systems. [Copyright &y& Elsevier]