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Preparation and Optical Limiting Properties of Polyurethane Containing Long Conjugated Chromophores.
- Source :
-
Journal of Macromolecular Science: Pure & Applied Chemistry . Jul2007, Vol. 44 Issue 7, p691-697. 7p. 1 Diagram, 1 Chart, 8 Graphs. - Publication Year :
- 2007
-
Abstract
- Two functional polyurethanes (P1 and P2) bearing a large π electron conjugated chromophoric pendant were synthesized and characterized by FT-IR, 1H-NMR and UV-Vis absorption spectra. Their optical limiting properties were evaluated. The results show that P1 and P2 show novel optical limiting properties, which are assigned to a long π electron conjugated chromophoric pendant. It was found that their optical limiting properties were affected simultaneously by solution concentration and P2 displays a better optical limiting property than P1 at the same solution transmittance, although that P1 has larger χ(3) (4.28×10-11 esu) than P2 (0.87×10-11 esu), and their optical limiting mechanism is investigated. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10601325
- Volume :
- 44
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Journal of Macromolecular Science: Pure & Applied Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 24953212
- Full Text :
- https://doi.org/10.1080/10601320701351193