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Bromidobis(pyrrolidine-1-dithiocarboxylato-κ2 S, S′)antimony(III).

Authors :
Jun Zhai
Qian-Xiu Pan
Han-Dong Yin
Feng Li
Da-Qi Wang
Source :
Acta Crystallographica: Section E. May2007, Vol. 63 Issue 5, pm1356-m1357. 1p. 3 Diagrams, 1 Chart.
Publication Year :
2007

Abstract

In the title compound, [SbBr(C5H8NS2)2], the SbIII ion is coordinated by the four S atoms [Sb—S = 2.4616 (11)–2.9194 (13) Å] from two pyrrolidine-1-dithiocarboxylate ligands and a Br atom [Sb—Br = 2.8159 (7) Å] in a distorted trigonal–bipyramidal geometry. In the crystal structure, the molecules are associated into dimers with short intermolecular Sb...S contacts of 3.7350 (13) Å. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
5
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
25054674
Full Text :
https://doi.org/10.1107/S1600536807016364