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Metal free in situ formation of phthalimide N-oxyl radicals by light-induced homolysis of N-alkoxyphthalimides

Authors :
Lucarini, Marco
Ferroni, Fiammetta
Pedulli, Gian Franco
Gardi, Stefano
Lazzari, Dario
Schlingloff, Gunther
Sala, Massimiliano
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jul2007, Vol. 48 Issue 30, p5331-5334. 4p.
Publication Year :
2007

Abstract

Abstract: Irradiation of N-triphenylmethyloxy- or N-diphenylmethyloxy phthalimide is reported to result in the formation of phthalimide N-oxyl radical (PINO), which is able to initiate and propagate oxidative radical chain reactions of hydrocarbons. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
48
Issue :
30
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
25567284
Full Text :
https://doi.org/10.1016/j.tetlet.2007.05.162