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Metal-Halide Bond Photoactivation from a PtIII-AuII Complex.
- Source :
-
Journal of the American Chemical Society . 8/22/2007, Vol. 129 Issue 33, p10094-10095. 2p. 1 Diagram, 1 Graph. - Publication Year :
- 2007
-
Abstract
- The article describes the preparation and characterization of the first PtAu compound. According to the authors, the d7-d9 complex exhibits a facile two-electron chemically assisted halogen photoelimination that is promoted by visible light. They add the electronic absorption spectrum of platinum compound features a dominant band centered at 338 nm.
- Subjects :
- *PLATINUM compounds
*METAL complexes
*HALOGENS
*ELECTRONS
*ABSORPTION spectra
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 129
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 26356810
- Full Text :
- https://doi.org/10.1021/ja073908z