Back to Search
Start Over
Crystal structure of a new complex of [3-(1H-benzimidazol-yl)propionato-N][3-(1H-benzimidazol-yl) propionic acid-N]silver(I), C20H19AgN4O4.
- Source :
-
Journal of Coordination Chemistry . 9/15/2007, Vol. 60 Issue 18, p1983-1987. 5p. 3 Diagrams. - Publication Year :
- 2007
-
Abstract
- The silver and acid hydrogen atoms in the crystal structure of [Ag(pa)(Hpa)]n (Hpa = 3-(1H-benzimidazol-2-yl) propionic acid-N) both lie on special positions of -1 site symmetry; the silver atom shows linear coordination [Ag-N = 2.109(3) Å, N-Ag-N = 180°]. The 'acid hydrogen' links molecules into a linear chain, and hydrogen bonds between the nitrogen-bound hydrogen atom and the carbonyl oxygen atom of an adjacent chain furnish a three-dimensional supramolecular structure. The compound, C20H19AgN4O4, belongs to the triclinic space group P1 [a = 6.536(7), b = 8.127(9), c = 9.051(1) Å; α = 81.692(2), β = 82.819(2), γ = 87.229(2)°], and there is one formula unit in the unit cell. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SILVER
*HYDROGEN bonding
*CRYSTALS
*PROPIONIC acid
*NITROGEN
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 60
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26461371
- Full Text :
- https://doi.org/10.1080/00958970701219954