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Photocatalytic selective aerobic oxidation of alcohols to aldehydes and ketones by HPW/MCM-41 in ionic liquids
- Source :
-
Journal of Molecular Catalysis A: Chemistry . Oct2007, Vol. 276 Issue 1/2, p73-79. 7p. - Publication Year :
- 2007
-
Abstract
- Abstract: The selective oxidation of alcohols with molecular oxygen was efficiently completed in high conversion and selectivity using HPW/MCM-41 as a heterogeneous photocatalyst in ionic liquids, [bmim]PF6, [omim]BF4 and [hmim]BF4. Comparative studies on the catalytic properties of HPW/MCM-41, HPW to MCM-41 were carried out. Some important variables, e.g. the loading amount of HPW on MCM-41 and the effects of different ionic liquids were discussed in this work. [Copyright &y& Elsevier]
- Subjects :
- *ALCOHOL
*ALCOHOLS (Chemical class)
*ORGANIC compounds
*ALCOHOL ethoxylates
Subjects
Details
- Language :
- English
- ISSN :
- 13811169
- Volume :
- 276
- Issue :
- 1/2
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Catalysis A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 26577587
- Full Text :
- https://doi.org/10.1016/j.molcata.2007.05.045