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Heterovalent clusters: Ln4Se(SePh)8 (Ln4 = Sm4, Yb4, Sm2Yb2, Nd2Yb2).

Authors :
Freedman, Deborah
Sayan, Safak
Source :
Journal of the American Chemical Society. 12/22/99, Vol. 121 Issue 50, p11713. 7p. 1 Diagram, 3 Charts, 2 Graphs.
Publication Year :
1999

Abstract

Examines synthesis and characterization of homologous tetranuclear (DME)4Ln4SePh)8 clusters (Ln = Sm, Yb, Nd(III)/Yb(II),Sm(III)/Yb(II); DME = dimethoxyethane). Reasons for analyzing stepwise sequence of clusters; Revelation of a square array of four metal ions; Relevance of cluster intermediates on Ln chalcogenido cluster synthesis.

Details

Language :
English
ISSN :
00027863
Volume :
121
Issue :
50
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
2733383
Full Text :
https://doi.org/10.1021/ja991437d