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Highly Enantioselective Insertion of Carbenoids into O—H Bonds of Phenols: An Efficient Approach to Chiral α-Aryloxycarboxylic Esters.
- Source :
-
Journal of the American Chemical Society . 10/24/2007, Vol. 129 Issue 42, p12616-12617. 2p. 2 Charts. - Publication Year :
- 2007
-
Abstract
- The article discusses the highly enantio selective insertion of carbenoids into oxygen-hydrogen bonds phenols, which is considered an effective approach to chiral α-aryloxycarboxylic esters. It is inferred that the enatioselectivity waned when the Cu/biazaferrocene catalyst was applied to phenol substrates. Moreover, the optically active α-arloxypropionates and the related acids were synthesized conveniently using the copper complexes of chiral spiro bisoxazolines as crystalysts.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 129
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 27422747
- Full Text :
- https://doi.org/10.1021/ja074729k