Back to Search
Start Over
Structures and nonlinear optical properties of molecular crystals DMCC and DBCC
- Source :
-
Journal of Molecular Structure . Dec2007, Vol. 871 Issue 1-3, p1-5. 5p. - Publication Year :
- 2007
-
Abstract
- Abstract: Structures and nonlinear optical properties of dimethylcroconate (DMCC) and dibenzoylcroconate (DBCC) are reported. The SHG active DMCC crystal packed in non-centrosymmetric P212121 space group. The DBCC crystal has a host–guest structure and crystallized in centrosymmetric P21/n space group. In DBCC crystal, the host DBCC molecules build channels along the b direction with the guest benzene molecules trapped in the channels. DSC, XRD, SHG and structural studies reveal that these benzene molecules can be removed at 90°C, accompanying the loss of the centro-symmetry and resulting in the SHG active new crystalline phase. [Copyright &y& Elsevier]
- Subjects :
- *MOLECULES
*BENZENE
*AROMATIC compounds
OPTICAL properties of molecular crystals
Subjects
Details
- Language :
- English
- ISSN :
- 00222860
- Volume :
- 871
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Structure
- Publication Type :
- Academic Journal
- Accession number :
- 27447042
- Full Text :
- https://doi.org/10.1016/j.molstruc.2007.01.041