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Bis{1-[bis(2-aminoethyl)amino]propan-2-ol}nickel(II) bis(perchlorate).

Authors :
Bao-Hua Qian
Zhen-Ming Zhang
Lu-De Lu
Xu-Jie Yang
Xin Wang
Source :
Acta Crystallographica: Section E. Nov2007, Vol. 63 Issue 11, pm2754-m2754. 1p. 4 Diagrams, 1 Chart.
Publication Year :
2007

Abstract

In the title compound, [Ni(C7H19N3O)2](ClO4)2, the Ni atom, which is located on an inversion center, is hexacoordinated by six N atoms from two ligands, forming a distorted octahedron. The complex molecules are linked by N—H...O hydrogen bonding, forming a one-dimensional chain structure along the a axis, which is further hydrogen bonded with the perchlorate anion to form a three-dimensional framework. One —CH2—CH2— group is disordered over two positions; the site occupancy factors are ca. 0.6 and 0.4. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16005368
Volume :
63
Issue :
11
Database :
Academic Search Index
Journal :
Acta Crystallographica: Section E
Publication Type :
Academic Journal
Accession number :
27533405
Full Text :
https://doi.org/10.1107/S1600536807050386