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Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand.

Authors :
Ya-Qian Lan
Shun-Li Li
Zhong-Min Su
Kui-Zhan Shao
Jian-Fang Ma
Xin-Long Wang
En-Bo Wang
Source :
Chemical Communications. Dec2007, Vol. 2008 Issue 1, p58-60. 3p.
Publication Year :
2007

Abstract

Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26]4− polyoxoanion and mixed valence Cu(i/ii) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
2008
Issue :
1
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
28021918