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Efficient intramolecular hydroamination of aminoalkynes catalyzed by a zirconium(IV) complex

Authors :
Kim, Hyunseok
Livinghouse, Tom
Lee, Phil Ho
Source :
Tetrahedron. Mar2008, Vol. 64 Issue 11, p2525-2529. 5p.
Publication Year :
2008

Abstract

Abstract: The neutral zirconium(IV) bis(thiophosphinic amidate) complex was demonstrated to be an effective precatalyst for 5-exo-, 6-exo-, and 7-exo-dig intramolecular hydroamination of aminoalkynes, producing the cyclic imines in excellent yields (92–98%). [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404020
Volume :
64
Issue :
11
Database :
Academic Search Index
Journal :
Tetrahedron
Publication Type :
Academic Journal
Accession number :
29376077
Full Text :
https://doi.org/10.1016/j.tet.2008.01.031