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Synthesis, crystal structure and saturable absorption in the near-IR regions of a new copper complex of dmit: hexadecyltrimethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-copper.

Authors :
Wang, Yan-Ling
Xu, Dong
Yu, Wen-Tao
Sun, Xiang-Bing
Ren, Quan
Zhang, Guang-hui
Ding, Yun-Qiao
Wang, Xin-qiang
Guo, Wen-feng
Chen, Hong-Yu
Feng, Lin
Source :
Journal of Coordination Chemistry. Mar2008, Vol. 61 Issue 5, p768-775. 8p. 3 Diagrams, 3 Charts, 2 Graphs.
Publication Year :
2008

Abstract

A new copper complex of dmit, hexadecyltrimethylammonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)-copper([C16H33(CH3)3N][Cu(dmit)2], abbreviated as CTCU, C16H33(CH3)3N = hexadecyltrimethylammonium, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate) has been synthesized and its structure determined by X-ray diffraction. The saturable absorption of CTCU at 1053 nm shows promise as a Q-switch dye in the near IR regions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00958972
Volume :
61
Issue :
5
Database :
Academic Search Index
Journal :
Journal of Coordination Chemistry
Publication Type :
Academic Journal
Accession number :
31134515
Full Text :
https://doi.org/10.1080/00958970701377208