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Physical organic chemistry of transition metal carbene complexes. 19. Kinetics of reversible....
- Source :
-
Journal of the American Chemical Society . 04/26/2000, Vol. 122 Issue 16, p3821. 9p. 9 Charts, 5 Graphs. - Publication Year :
- 2000
-
Abstract
- Part XIX. Investigates the effect of the nucleophilic addition of MeO- to Fischer carbene complexes. Formation of tetrahedral adducts; Observance of imbalance in the transition state of alkoxide ion in the addition of carbene complexes; Description of proton transfer to the leaving group in the carbon-oxygen bond cleavage.
- Subjects :
- *CARBENES
*NUCLEOPHILIC reactions
*ORGANOTRANSITION metal compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 122
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 3139047
- Full Text :
- https://doi.org/10.1021/ja994174w