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Physical organic chemistry of transition metal carbene complexes. 19. Kinetics of reversible....

Authors :
Bernasconi, Claude F.
Garcia-Rio, Luis
Source :
Journal of the American Chemical Society. 04/26/2000, Vol. 122 Issue 16, p3821. 9p. 9 Charts, 5 Graphs.
Publication Year :
2000

Abstract

Part XIX. Investigates the effect of the nucleophilic addition of MeO- to Fischer carbene complexes. Formation of tetrahedral adducts; Observance of imbalance in the transition state of alkoxide ion in the addition of carbene complexes; Description of proton transfer to the leaving group in the carbon-oxygen bond cleavage.

Details

Language :
English
ISSN :
00027863
Volume :
122
Issue :
16
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
3139047
Full Text :
https://doi.org/10.1021/ja994174w