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Synthesis and properties of a new SASRIN resin derivative: SASRIN–2-pyridylthiocarbonate (SASRIN–TOPCAT) resin
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Apr2008, Vol. 49 Issue 18, p2951-2955. 5p. - Publication Year :
- 2008
-
Abstract
- Abstract: A new SASRIN resin derivative, SASRIN–TOPCAT resin, was synthesized by the reaction of SASRIN resin with 2-thiopyridyl chloroformate. The new resin can be used for the loading of alcohols and thiols under neutral conditions, and the release of alcohol from the resin is achieved by the treatment of 1% TFA in CH2Cl2 for 15–60min. Compared to the other reported resins, SASRIN–TOPCAT resin is more suitable for the loading of alcohols in solid-phase organic synthesis. [Copyright &y& Elsevier]
- Subjects :
- *ALCOHOL
*ALCOHOLS (Chemical class)
*THIOLS
*ORGANOSULFUR compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 49
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31558918
- Full Text :
- https://doi.org/10.1016/j.tetlet.2008.03.017