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Resonance Raman, optical spectroscopic, and EPR characterization of the higher oxidation states....

Authors :
Yamada, Hiroshi
Hurst, James K.
Source :
Journal of the American Chemical Society. 06/07/2000, Vol. 122 Issue 22, p5303. 9p. 11 Graphs.
Publication Year :
2000

Abstract

Examines the structural characterization of higher oxidation states of the water oxidation catalyst. Use of Resonance Raman (RR) and optical spectroelectrochemical titrations; Estimation of rate constants; Structure of frozen ion solutions; Consistency of the RR spectrum with the coordination of terminal oxo ligands by cerium4+.

Details

Language :
English
ISSN :
00027863
Volume :
122
Issue :
22
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
3259873
Full Text :
https://doi.org/10.1021/ja993914y