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Novel Cd(II) and Co(II) 2-D frameworks based on terephthalate and 1-substitutedimidazole mixed-ligands
- Source :
-
Inorganic Chemistry Communications . Jul2008, Vol. 11 Issue 7, p809-813. 5p. - Publication Year :
- 2008
-
Abstract
- Abstract: The two Cd(II) and Co(II) 2-D frameworks have been prepared by means of self-assemblies of Cd(II) or Co(II) salts and 1-substituted imidazole and terephthalic acid, and structurally characterized by X-ray diffraction analyses. In complex 1 2-D frameworks with rhombic cavity are formed, in which the each top point of rhombus contains one hexa and two heptacoordinated Cd(II). In complex 2 2-D networks with rectangular cavities are formed, and the opposite benzene rings from carboxyls in each rectangular cavity are parallel. [Copyright &y& Elsevier]
- Subjects :
- *CADMIUM
*COBALT
*TEREPHTHALIC acid
*LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 11
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 32665212
- Full Text :
- https://doi.org/10.1016/j.inoche.2008.04.009