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High-Yield Synthesis of 1,3-Dimesityl-propane-1,3-dione: Isolation of Its Aluminum Complex as a Stable Intermediate.
- Source :
-
Synthetic Communications . 2008, Vol. 38 Issue 14, p2349-2356. 8p. 3 Diagrams, 2 Charts. - Publication Year :
- 2008
-
Abstract
- 1,3-Dimesityl-propane-1,3-dione was synthesized in high yield, via a stable intermediate (its aluminum complex) from malonyl dichloride and mesitylene by Friedel-Crafts reaction using anhydrous aluminum chloride as catalyst. The intermediate aluminum complex was isolated and characterized by X-ray diffraction analysis, which decomposed upon reflux in concentrate hydrochloric acid to give the title compound. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALUMINUM
*PROPANE
*FRIEDEL-Crafts reaction
*MESITYLENE
*CATALYSTS
*CHEMISTRY
Subjects
Details
- Language :
- English
- ISSN :
- 00397911
- Volume :
- 38
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Synthetic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 33140909
- Full Text :
- https://doi.org/10.1080/00397910802138702