Stepwise formation of “organometallic boxes” with half-sandwich Ir, Rh and Ru fragments.

Authors :: Ying-Feng Han
Yue-Jian Lin
Lin-Hong Weng
Heinz Berke
Guo-Xin Jin
Source :: Chemical Communications. Jan2008, Vol. 2008 Issue 3, p350-352. 3p.
Publication Year :: 2008
Abstract: Octanuclear complexes with half-sandwich Ir, Rh and Ru fragments and tetra(4-pyridyl)porphyrin (L1) and oxalate (L2) spacer ligands [(Cp*M)4L1]2[L2]4 (M = Ir (6a) M = Rh (6b)), [((cymene)Ru)4(L1)]2[L2]4 were prepared and characterized. [ABSTRACT FROM AUTHOR]

Subjects :: *ORGANOMETALLIC chemistry
*COMPLEX compounds
*IRIDIUM
*RHODIUM
*RUTHENIUM
*LIGANDS (Chemistry)
*COORDINATION compounds

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