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Factors Involved in the Nuclearity of Silver Thiosemicarbazone Clusters: Cocrystallization of Two Different Sized Tetranuclear Silver(l) Clusters Derived from a Phosphinothiosemicarbazone Ligand.
- Source :
-
Inorganic Chemistry . 7/7/2008, Vol. 47 Issue 13, p5534-5536. 3p. 2 Diagrams, 1 Graph. - Publication Year :
- 2008
-
Abstract
- The reaction of silver acetate with a phosphinothiosemicarbazone ligand, HLPPh, yielded the tetranuclear silver compound [Ag4(LPPh)4] · 2MeOH (1), which after recrystallization results in the cocrystallization of two different silver clusters, [Ag4(LPPh)4]a- [Ag4(LPPh)4]b · 8MeOH (2). The factors involved in the assembly of tetranuclear compounds derived from thiosemicarbazone ligands and the structural differences between the two clusters are analyzed herein. Additionally, HLPPh and complex 1 exhibit photoluminescence in solution at room temperature. [ABSTRACT FROM AUTHOR]
- Subjects :
- *THIOSEMICARBAZONES
*CRYSTALLIZATION
*SILVER
*LIGANDS (Chemistry)
*PHOTOLUMINESCENCE
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 47
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 33262362
- Full Text :
- https://doi.org/10.1021/ic800178v