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Syntheses, structures and fluorescent properties of three copper cyanide coordination polymers based on N-heterocyclic ligands.
- Source :
-
Journal of Coordination Chemistry . Sep2008, Vol. 61 Issue 18, p2999-3007. 9p. 3 Diagrams, 4 Charts, 1 Graph. - Publication Year :
- 2008
-
Abstract
- Hydrothermal reactions of CuCN, K3[Fe(CN)6] with 2,2'-bipyridine, 1,10-phenanthroline or 2,6-bis(1,2,4-triazolyl)pyridine (btp) afford three coordination polymers, [Cu7(CN)7(bipy)2]n (1), [Cu2(CN)2(phen)]n (2) and [Cu3(CN)3(btp)]n (3). Complex 1 displays 1D polymeric ribbons which are assembled through Cu ··· Cu and π-π stacking interactions into a 3D framework. Complex 2 shows a 1D zigzag chain structure in which phen is a side ligand. In 3, the copper cyanide 2D polymeric networks are connected by tridentate btp to form a 3D metal-organic framework. These coordination polymers exhibit strong fluorescent emissions in the solid state. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BIPYRIDINE
*PYRIDINE
*POLYMERS
*FLUORESCENCE
*CYANIDES
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 61
- Issue :
- 18
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 33881202
- Full Text :
- https://doi.org/10.1080/00958970801995701