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Electrochemical performance of Pr0.7Sr0.3Co0.9Cu0.1O3−δ –Ce0.8Sm0.2O1.9 composite cathodes in intermediate-temperature solid oxide fuel cells
- Source :
-
Journal of Power Sources . Oct2008, Vol. 185 Issue 1, p212-216. 5p. - Publication Year :
- 2008
-
Abstract
- Abstract: The electrochemical performance of Pr0.7Sr0.3Co0.9Cu0.1O3−δ –xCe0.8Sm0.2O1.9 (PSCC–xSDC, x =0–40wt%) composite cathodes has been investigated for their potential utilization in intermediate-temperature solid oxide fuel cells (SOFCs). The results showed that the addition of SDC to PSCC improved remarkably the electrochemical performance of a PSCC cathode, and that a PSCC–35SDC cathode exhibited the best electrochemical performance in the PSCC–xSDC system. When SDC was used as the electrolyte, the interfacial resistance was smallest for 35wt% SDC, where the value was 0.137Ωcm2 at 700°C and 0.062Ωcm2 at 750°C, much lower than the corresponding interfacial resistance for pure PSCC. At 700°C, the cathodic overpotential of the PSCC–35SDC cathode in the SDC electrolyte was 70mV at a current density of 0.5Acm−2. This is a factor of two lower than that for a pure PSCC cathode (152mV at 700°C) under the same current conditions. The maximum power density of a single-cell using PSCC–35SDC as the cathode was 388 and 615mWcm−2 at 650 and 700°C, respectively. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 185
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 34297489
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2008.06.027