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Syntheses, structures and thermal stabilities of four complexes with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand
- Source :
-
Journal of Molecular Structure . Nov2008, Vol. 891 Issue 1-3, p50-57. 8p. - Publication Year :
- 2008
-
Abstract
- Abstract: Reactions of 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-abpt) with metal acetates gave rise to four new complexes [Cu(3-abpt)(ip)] n ·2nH2O (1), [Co(3-abpt)(ip)(H2O)2] n ·2nH2O (2), [Ni(3-abpt)(tp)(H2O)2] n (3) and [Cu(3-abpt)2(CH3COO)2(H2O)2] (4) (ip=isophthalate, tp=terephthalate), which were characterized by EA, IR and X-ray crystallography. Compound 1 consists of two kinds of ring-like chain which are interconnected to form an unusual two-dimensional layered motif. Compounds 2 and 3 are both 1D ring-like infinite chains. Compound 4 is a mononuclear complex. The thermal stabilities of coordination polymers 1–3 have been investigated. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00222860
- Volume :
- 891
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Journal of Molecular Structure
- Publication Type :
- Academic Journal
- Accession number :
- 35206047
- Full Text :
- https://doi.org/10.1016/j.molstruc.2008.03.011