Comparison of electrothermal and hydride generation atomic absorption spectrometry for the determination of total arsenic in broiler chicken

Abstract: The purpose of this study was to estimate total arsenic concentration in different tissues (leg, breast, liver and heart) of broiler chicken by hydride generation atomic absorption spectrometry (HGAAS) and graphite furnace atomic absorption spectrometry (GFAAS), prior to microwave assisted acid digestion. The accuracy of the techniques was evaluated by using certified reference material DORM-2. The percentage recoveries of total As were observed as 100.6% and 99.4% for HGAAS and GFAAS, respectively. The precision of the techniques, expressed as relative standard deviation, was observed as 1.71% and 4.18% for HGAAS and GFAAS measurements, respectively. The limits of detection for HGAAS and GFAAS were 0.025μg/g and 0.052μg/g, respectively. The concentrations of total arsenic in different tissues of broiler chicken were found in the range of 2.19–5.28, 2.15–5.22, 2.97–7.17 and 2.68–6.36μg/g for leg, breast, liver and heart tissues, respectively. At a mean level of chicken consumption (60g/person/day), people may ingest in the range of 72.0–85.1μg arsenic/person/day from chicken alone. [Copyright &y& Elsevier]