Copper iodide-catalyzed aziridination of alkenes with sulfonamides and sulfamate esters

Authors :: Chang, Joyce Wei Wei
Ton, Thi My Uyen
Zhang, Zhengyang
Xu, Yanjun
Chan, Philip Wai Hong
Source :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Jan2009, Vol. 50 Issue 2, p161-164. 4p.
Publication Year :: 2009
Abstract: Abstract: An efficient copper iodide-catalyzed aziridination of a variety of alkenes with sulfonamides and sulfamate esters as the nitrogen source and iodosylbenzene (PhI oxidant is reported herein. The reaction is operationally straightforward, applicable to a variety of alkenes containing electron-withdrawing, electron-donating, and sterically encumbered substrate combinations, and proceeds under mild conditions at room temperature in good to excellent yields. [Copyright &y& Elsevier]

Subjects :: *CUPROUS iodide
*CATALYSIS
*ALKENES
*SULFONAMIDES
*ESTERS
*CHEMICAL reactions

Language :: English
ISSN :: 00404039
Volume :: 50
Issue :: 2
Database :: Academic Search Index
Journal :: Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :: Academic Journal
Accession number :: 35557653
Full Text :: https://doi.org/10.1016/j.tetlet.2008.10.105

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