Back to Search
Start Over
Hydrothermal synthesis, structure and rare ferromagnetic property of a 3-D Nd(III) metal–organic framework based on mixed pyridine-2,5-dicarboxylic acid/nicotinic acid ligands
- Source :
-
Inorganica Chimica Acta . Jan2009, Vol. 362 Issue 1, p299-302. 4p. - Publication Year :
- 2009
-
Abstract
- Abstract: A novel 3-D metal–organic framework Nd(2,5-pydc)(nic)(H2O) (1, 2,5-pydc=pyridine-2,5-dicarboxylic acid, nic=nicotinic acid) has been hydrothermally synthesized and characterized by elemental analyses, IR, and X-ray single-crystal diffraction. Compound 1 is the first MOF based on mixed 2,5-pydc/nic ligands. The title compound displays an interseting 3-D (6,3)-connected network with the topology of (4.62)2(42 ×610 ×83). Magnetic susceptibility measurements show that compound1 presents a rare ferromagnetic interaction between two adjacent Nd(III) ions. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 362
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 35561448
- Full Text :
- https://doi.org/10.1016/j.ica.2008.03.103