Detecting anomalous CO2 flux using space borne spectroscopy

Abstract: Over the time-scale, earth''s atmospheric CO2 concentration has varied and that is mostly determined by balance among the geochemical processes including burial of organic carbon in sediments, silicate rock weathering and volcanic activity. The best recorded atmospheric CO2 variability is derived from Vostok ice core that records last four glacial/interglacial cycles. The present CO2 concentration of earth''s atmosphere has exceeded far that it was predicted from the ice core data. Other than rapid industrialization and urbanization since last century, geo-natural hazards such as volcanic activity, leakage from hydrocarbon reservoirs and spontaneous combustion of coal contribute a considerable amount of CO2 to the atmosphere. Spontaneous combustion of coal is common occurrence in most coal producing countries and sometimes it could be in an enormous scale. Remote sensing has already proved to be a significant tool in coalfire identification and monitoring studies. However, coalfire related CO2 quantification from remote sensing data has not endeavoured yet by scientific communities because of low spectral resolution of commercially available remote sensing data and relatively sparse CO2 plume than other geological hazards like volcanic activity. The present research has attempted two methods to identify the CO2 flux emitted from coalfires in a coalmining region in north China. Firstly, a band rationing method was used for column atmospheric retrieval of CO2 and secondly atmospheric models were simulated in fast atmospheric signature code (FASCOD) to understand the local radiation transport and then the model was implemented with the inputs from hyperspectral remote sensing data. It was observed that retrieval of columnar abundance of CO2 with the band rationing method is faster as less simulation required in FASCOD. Alternatively, the inversion model could retrieve CO2 concentration from a (certain) source because it excludes the uncertainties in the higher altitude. [Copyright &y& Elsevier]