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Total synthesis of (+)-acutiphycin and (+)-trans-20,21-didehydroacutiphycin.

Authors :
Smith III, Amos B.
Chen, Sean S.-Y.
Nelson, Frances C.
Reichert, Janice M.
Salvatore, Brian A.
Source :
Journal of the American Chemical Society. 11/12/97, Vol. 119 Issue 45, p10935. 12p.
Publication Year :
1997

Abstract

Discusses the synthesis of the cytotoxic macrolides (+)-acutiphycin and (+)-trans-20,21-didehydroacutiphycin. Construction of common advanced aldehyde; Synthesis of vinyl bromides; Methods for macrolactone generation; Metabolites produced by the source of the blue-green alga Osillatoria acutissima.

Details

Language :
English
ISSN :
00027863
Volume :
119
Issue :
45
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
35887
Full Text :
https://doi.org/10.1021/ja972497r