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Synthesis and structure of the lithium, zirconium and hafnium N-silyl-N′-benzyl-benzamidinates
- Source :
-
Inorganica Chimica Acta . Jan2009, Vol. 362 Issue 2, p583-586. 4p. - Publication Year :
- 2009
-
Abstract
- Abstract: The interaction of LiN(SiMe3)CH2Ph with one equivalent of benzenitrile gave the N-silyl-N′-benzyl-benzamidinato-lithium compound [{Me3SiNC(Ph)N(CH2Ph)}Li(Et2O)]2 (1). The derivative zirconium and hafnium compounds were produced by the treatment of 1 with ZrCl4 or HfCl4 in tetrahydrofuran or diethyl ether at ambient temperature, respectively, with the general formula [Me3SiNC(Ph)N(CH2Ph)]3MCl (M=Zr (2), Hf (3)). Compounds 1, 2 and 3 were also characterized by X-ray single crystal diffraction and NMR analysis. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00201693
- Volume :
- 362
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Inorganica Chimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 36049188
- Full Text :
- https://doi.org/10.1016/j.ica.2008.03.112