Metal–organic replica of γ-Pu: the first uninodal 10-connected coordination network based on pentanuclear cadmium clustersElectronic supplementary information (ESI) available: Mineral topologies that have been imitated in MOFs, PXRD, and Fig. S1–S5. CCDC 700746. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b815629h

The first uninodal 10-connected metal–organic framework, based on pentanuclear cadmium cluster building blocks, exhibits an unprecedented γ-Pu topology, which adds a new member to the series of metal–organic analogues which have a natural materials topology. [ABSTRACT FROM AUTHOR]