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Effects of oversized solutes on radiation-induced segregation in austenitic stainless steels
- Source :
-
Journal of Nuclear Materials . May2009, Vol. 389 Issue 2, p265-278. 14p. - Publication Year :
- 2009
-
Abstract
- Abstract: Zirconium or hafnium additions to austenitic stainless steels caused a reduction in grain boundary Cr depletion after proton irradiations for up to 3dpa at 400°C and 1dpa at 500°C. The predictions of a radiation-induced segregation (RIS) model were also consistent with experiments in showing greater effectiveness of Zr relative to Hf due to a larger binding energy. However, the experiments showed that the effectiveness of the solute additions disappeared above 3dpa at 400°C and above 1dpa at 500°C. The loss of solute effectiveness with increasing dose is attributed to a reduction in the amount of oversized solute from the matrix due to growth of carbide precipitates. Atom probe tomography measurements indicated a reduction in amount of oversized solute in solution as a function of irradiation dose. The observations were supported by diffusion analysis suggesting that significant solute diffusion by the vacancy flux to precipitate surfaces occurs on the time scales of proton irradiations. With a decrease in available solute in solution, improved agreement between the predictions of the RIS model and measurements were consistent with the solute-vacancy trapping process, as the mechanism for enhanced recombination and suppression of RIS. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00223115
- Volume :
- 389
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Nuclear Materials
- Publication Type :
- Academic Journal
- Accession number :
- 37817908
- Full Text :
- https://doi.org/10.1016/j.jnucmat.2009.02.010