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Structural study of FeP2 at high pressure.
- Source :
-
High Pressure Research . Jun2009, Vol. 29 Issue 2, p235-244. 10p. 1 Color Photograph, 2 Charts, 7 Graphs. - Publication Year :
- 2009
-
Abstract
- The structural stability of marcasite-type FeP2 at high pressure has been studied by X-ray diffraction, Raman spectroscopy, and theoretical calculations. Experimental results show that no phase transitions happen up to 28 GPa at room temperature. The shortest axis of the marcasite-type FeP2 cell, the c-axis, is the most compressible, due to the softening of edge-shared octahedra along the c-axis. The linear pressure coefficients and Gruneisen parameters of four Raman modes are determined. Theoretical calculations further support the experimental results and indicate that FeP2 is still a semiconductor up to 35 GPa. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08957959
- Volume :
- 29
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- High Pressure Research
- Publication Type :
- Academic Journal
- Accession number :
- 39982557
- Full Text :
- https://doi.org/10.1080/08957950802597221