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Physical Organic Chemistry of Transition Metal Carbene Complexes. 21. Kinetics and Mechanism....

Authors :
Bernasconi, Claude F.
Perez, Gabriel S.
Source :
Journal of the American Chemical Society. 12/20/2000, Vol. 122 Issue 50, p12441. 6p. 1 Diagram, 1 Chart, 2 Graphs.
Publication Year :
2000

Abstract

Investigates the kinetics and mechanism of hydrolysis of transition metal carbene complexes in aqueous acetonitrile. Stages of the reactions; Reactivity differences between metal carbene complexes and complexes with alkoxy leaving groups; Factors affecting the reactivity ratios.

Details

Language :
English
ISSN :
00027863
Volume :
122
Issue :
50
Database :
Academic Search Index
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
4043529
Full Text :
https://doi.org/10.1021/ja002371l