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Physical Organic Chemistry of Transition Metal Carbene Complexes. 21. Kinetics and Mechanism....
- Source :
-
Journal of the American Chemical Society . 12/20/2000, Vol. 122 Issue 50, p12441. 6p. 1 Diagram, 1 Chart, 2 Graphs. - Publication Year :
- 2000
-
Abstract
- Investigates the kinetics and mechanism of hydrolysis of transition metal carbene complexes in aqueous acetonitrile. Stages of the reactions; Reactivity differences between metal carbene complexes and complexes with alkoxy leaving groups; Factors affecting the reactivity ratios.
- Subjects :
- *CARBENES
*TRANSITION metals
*CHEMICAL kinetics
*ACETONITRILE
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 122
- Issue :
- 50
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 4043529
- Full Text :
- https://doi.org/10.1021/ja002371l