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Growth and thermoelectric properties of Ba8Ga16Ge30 clathrate crystals
- Source :
-
Journal of Alloys & Compounds . Aug2009, Vol. 482 Issue 1/2, p544-547. 4p. - Publication Year :
- 2009
-
Abstract
- Abstract: Ba8Ga16Ge30 clathrate crystals were grown by Czochralski method. The influence of growth condition on the composition and thermoelectric property of the obtained crystals was investigated. The lower pulling rate and higher pressure resulted in a larger Ga/Ge ratio in the grown crystals, and the elemental composition was homogeneous. The sample with a higher Ga/Ge ratio showed the larger electrical conductivity than the sample with a lower Ga/Ge ratio, but the Seebeck coefficient was not sensitive to the Ga/Ge ratio, which led to a larger power factor. The higher Ga/Ge ratio also resulted in a lower lattice thermal conductivity and as a result led to a higher ZT value, which was measured to be 0.93 at 850K and could reach 1.3 as extrapolated to 1000K. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 482
- Issue :
- 1/2
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 41584171
- Full Text :
- https://doi.org/10.1016/j.jallcom.2009.04.072