Homolytic reactivity of group 14 organometallic hydrides toward nitroxides.

Authors :: Lucarini, Marco
Marchesi, Emanuela
Pedulli, Gian Franco
Chatgilialoglu, Chryssosttomos
Source :: Journal of Organic Chemistry. 03/06/98, Vol. 63 Issue 5, p1687. 7p. 3 Diagrams, 4 Charts, 4 Graphs.
Publication Year :: 1998
Abstract: Examines the chemical reactions involving the tetramethyl-1-piperidinoxyl (TEMPO) compounds along with the related nitroxides. Characterization of the metal hydrides; Proposal of a mechanism for the reduction of TEMPO by the two trimethylsiyl-substituted silanes; Information on the behavior of the nitroxide radicals.