Fluorescence studies of electrospun MEH-PPV/PEO nanofibers

Abstract: We report a study of the fluorescence properties of the conjugated polymer poly [2-methoxy-5-(2′-ethyl hexyloxy)-p-phenylene vinylene] (MEH-PPV) and polyethylene oxide (PEO) nanofibers. MEH-PPV/PEO nanofibers with different compositions have been fabricated by the electrospinning technique. The fluorescence spectra of the nanofibers show that the emission shoulder at ∼630nm blue-shifts ∼45nm, whereas the main emission peak around 590nm blue-shifts ∼15nm with decreasing concentration of MEH-PPV in the nanofiber. In addition, confocal microscopic studies of a single MEH-PPV/PEO electrospun nanofiber indicate that the fluorescence spectra of the nanofiber do not show any polarization dependence. The results are discussed in terms of the aggregation of MEH-PPV in an inert matrix. [Copyright &y& Elsevier]