A critical approach to viscosity index

Abstract: The viscosity index (VI) is a useful tool for lubricant users and refiners, since it is a measure of the effect of temperature changes on the viscosity of the oil. However, it was found that the viscosity index does not correlate with the flow activation energy Ea , which is the theoretically defined dependence of the viscosity on temperature. In this way, two oils may have the same flow activation energy but a viscosity index varying by up to 120. We therefore believe that the VI does not always give a proper representation of the effect of temperature on the kinematic viscosity. 13C NMR spectroscopy was used to identify the molecules with a high VI. Twenty different oil samples produced from eight different vacuum gas oils with viscosity indices ranging from −104 to 146 were analyzed and key parameters identified for high VI molecules: long alkyl chains, methyl branching in the centre of the molecule, low content of aromatic compounds, no ethyl branching and no tertiary carbons. A correlation based on four selected peaks was developed, giving a very good prediction of the viscosity index. [Copyright &y& Elsevier]