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Fabrication of a high-strength hydrogel with an interpenetrating network structure
- Source :
-
Colloids & Surfaces A: Physicochemical & Engineering Aspects . Aug2009, Vol. 346 Issue 1-3, p91-98. 8p. - Publication Year :
- 2009
-
Abstract
- Abstract: Hydrogels have potential applications in many fields, but the poor mechanical strength has limited their further development. In this article, we designed a high-strength hydrogel with an interpenetrating network (IPN) structure from polyacrylamide (PAM) and poly(vinyl alcohol) (PVA). Synthesis parameters, such as PVA/AM mass ratio, crosslinker dosage and elongation time were carried out for high tensile strength and elongation. The results showed that chemical crosslinking, physical entanglement and PVA precipitates were the dominant parameters for the improvement of mechanical properties. The PVA structure transferred from crystal to amorphous due to intermolecular and intramolecular interactions (such as hydrogen bond and self-crosslinking). PVA precipitates scatterred in the brittle PAM matrix homogeneously which dispersed the applied stress and improved the hydrogel toughness. The tensile strength and elongation were extremely high, they were 2.4MPa and 3100%, respectively. The simple method is versatile in synthesizing high-strength IPN hydrogels using many kinds of polymer species. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 09277757
- Volume :
- 346
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Colloids & Surfaces A: Physicochemical & Engineering Aspects
- Publication Type :
- Academic Journal
- Accession number :
- 43409357
- Full Text :
- https://doi.org/10.1016/j.colsurfa.2009.05.031